Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(perchlorate) sesquihydrate
نویسندگان
چکیده
In the title complex, [Mn(C(13)H(14)N(2))(4)(H(2)O)(2)](ClO(4))(2)·1.5H(2)O, the Mn(II) ion is coordinated by four N atoms from four different 1,3-di-4-pyridyl-propane mol-ecules and two O atoms from two coordinated water mol-ecules, leading to a distorted MnN(4)O(2) octa-hedral geometry. Each 1,3-di-4-pyridyl-propane ligand displays a monodentate coordinating mode. In the crystal, there exist O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds. The perchlorate anions and the coordinated and lattice water mol-ecules play an important role in the formation of these hydrogen bonds. One of the two lattice water molecules shows half-occupancy.
منابع مشابه
catena-Poly[[[diaquacobalt(II)]bis(μ-1,3-di-4-pyridylpropane-κ2 N:N′)] bis(perchlorate) bis(1,3-di-4-pyridylpropane) bis(2-methyl-4-nitroaniline)]
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011